Chromatography

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Chromatography is a continuously evolving scientific discipline or field "studying the formation, change, movement, and separation of multiple concentration zones of chemical compounds (analytes or particles) of the studied sample in a flow of mobile phase relative to selective influence of one or a number of solid/liquid stationary phases or sorbents."[1]

Chromatography has numerous methods associated with, dependent on the process-specific movement and type of mobile phase[1]:

Methods of chromatography
Mobility or equilibria Phase Chromatography type
Liquid Tswett, paper, thin-layer
Gas Gas
Supercritical medium Supercritical fluid
Electrical flow Electro
Sorbent liquid Hypersorption, countercurrent, denuder
↓↑ Adsorption Liquid-solid (gel), gas-solid, supercritical fluid-solid
↓↑ Chemisorption Ion exchange, affinity, complex-forming
↓↑ Absorption (partition) Liquid-liquid, gas-liquid
↓↑ Physical field Field-flow fractionation
Equilibrium (isotherm) Techniques, channel Hyphenated mode
Linear Zone, column One-dimensional
Non-linear Frontal, slot Multidimensional
Non-linear Displacement, flat bed Combined with spectral methods

(Note: Arrows in the table indicate the movement of the analyte-containing mobile phase.)


See also

References

  1. 1.0 1.1 Wixom, Robert L. (ed); Gehrke, Charles W. (ed.); Berezkin, Viktor G.; Janak, Jaroslav (2011). "Chapter 1: Chromatography - A New Discipline of Science". Chromatography: A Science of Discovery. John Wiley & Sons. pp. 1–13. ISBN 1118060296. http://books.google.com/books?id=pKKoOCsytBMC.